Pure organic PU foam is typically Class B2 or B1 (GB 8624), with a limiting oxygen index of 22–26%. To achieve Class A non-combustible, a composite flame-retardant system is required: 1) Add inorganic fillers like melamine or expandable graphite to increase LOI above 32%; 2) Use reactive flame retardants (e.g., DMMP) grafted onto the polymer chain; 3) Laminate inorganic fiber mats (e.g., ceramic fiber) on the foam surface as a fire barrier; 4) Encapsulate the core with magnesium cement or magnesium oxysulfate board. Even with these measures, the strictest classification is Class A2 (total heat value ≤3 MJ/kg). Fully inorganic cores (e.g., stone wool) are true Class A1 but have poorer insulation. In engineering, fire-retardant PU sandwich panels are often used as Class B1, supplemented by sprinkler systems to meet codes.

